Episodes of That Metal Show are finally being broadcast in HD on the Palladia channel.  Here is season 13 episode 9.  The guest is Dee Snider (Twisted Sister) with guest guitarist Chris Caffery.

This video was captured directly from a digital cable box's HDMI output to MPEG4 in 1080i using a Game Capture HD and an HDMI splitter to remove HDCP.  HandBrake 0.9.9.5530 was then used to perform de-interlacing and reduction of the file size (without sacrificing much quality).  See below for complete technical specs on the video.

Screenshots:
 
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MediaInfo:

General
Complete name                            : D:uploadsThat Metal Show S13E09 HDTV 1080pThat Metal Show S13E09 HDTV 1080p.mp4
Format                                   : MPEG-4
Format profile                           : Base Media / Version 2
Codec ID                                 : mp42
File size                                : 1.93 GiB
Duration                                 : 43mn 39s
Overall bit rate mode                    : Variable
Overall bit rate                         : 6 326 Kbps
Movie name                               : That Metal Show
Description                              : Description here.
Recorded date                            : 2014-11-23
Encoded date                             : UTC 2014-11-24 15:39:22
Tagged date                              : UTC 2014-11-24 17:07:22
Writing application                      : HandBrake 0.9.9 2013052900

Video
ID                                       : 1
Format                                   : AVC
Format/Info                              : Advanced Video Codec
Format profile                           : [email protected]
Format settings, CABAC                   : Yes
Format settings, ReFrames                : 4 frames
Codec ID                                 : avc1
Codec ID/Info                            : Advanced Video Coding
Duration                                 : 43mn 39s
Bit rate                                 : 6 002 Kbps
Width                                    : 1 920 pixels
Height                                   : 1 078 pixels
Display aspect ratio                     : 16:9
Frame rate mode                          : Variable
Frame rate                               : 29.970 fps
Minimum frame rate                       : 2.028 fps
Maximum frame rate                       : 59.960 fps
Color space                              : YUV
Chroma subsampling                       : 4:2:0
Bit depth                                : 8 bits
Scan type                                : Progressive
Bits/(Pixel*Frame)                       : 0.097
Stream size                              : 1.83 GiB (95%)
Writing library                          : x264 core 130 r2273 b3065e6
Encoding settings                        : cabac=1 / ref=4 / deblock=1:0:0 / analyse=0x3:0x113 / me=umh / subme=8 / psy=1 / psy_rd=1.00:0.00 / mixed_ref=1 / me_range=16 / chroma_me=1 / trellis=1 / 8x8dct=1 / cqm=0 / deadzone=21,11 / fast_pskip=1 / chroma_qp_offset=-2 / threads=12 / lookahead_threads=2 / sliced_threads=0 / nr=0 / decimate=1 / interlaced=0 / bluray_compat=0 / constrained_intra=0 / bframes=3 / b_pyramid=2 / b_adapt=2 / b_bias=0 / direct=3 / weightb=1 / open_gop=0 / weightp=2 / keyint=600 / keyint_min=60 / scenecut=40 / intra_refresh=0 / rc_lookahead=50 / rc=crf / mbtree=1 / crf=20.0 / qcomp=0.60 / qpmin=0 / qpmax=69 / qpstep=4 / vbv_maxrate=62500 / vbv_bufsize=78125 / crf_max=0.0 / nal_hrd=none / ip_ratio=1.40 / aq=1:1.00
Encoded date                             : UTC 2014-11-24 15:39:22
Tagged date                              : UTC 2014-11-24 17:07:22
Color primaries                          : BT.709
Transfer characteristics                 : BT.709
Matrix coefficients                      : BT.709

Audio
ID                                       : 2
Format                                   : AAC
Format/Info                              : Advanced Audio Codec
Format profile                           : LC
Codec ID                                 : 40
Duration                                 : 43mn 39s
Bit rate mode                            : Variable
Bit rate                                 : 319 Kbps
Maximum bit rate                         : 382 Kbps
Channel(s)                               : 2 channels
Channel positions                        : Front: L R
Sampling rate                            : 48.0 KHz
Compression mode                         : Lossy
Stream size                              : 99.6 MiB (5%)
Language                                 : English
Encoded date                             : UTC 2014-11-24 15:39:22
Tagged date                              : UTC 2014-11-24 17:07:21